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  1. Two structurally different metal–organic frameworks based on Sr 2+ ions and 1,2,4,5-tetrakis(4-carboxyphenyl)benzene linkers have been synthesized solvothermally in different solvent systems and studied with single-crystal X-ray diffraction technique. These are poly[[μ 12 -4,4′,4′′,4′′′-(benzene-1,2,4,5-tetrayl)tetrabenzoato](dimethylformamide)distrontium(II)], [Sr 2 (C 34 H 18 O 8 )(C 3 H 7 NO) 2 ] n , and poly[tetraaqua{μ 2 -4,4′-[4,5-bis(4-carboxyphenyl)benzene-1,2-diyl]dibenzoato}tristrontium(II)], [Sr 3 (C 34 H 20 O 8 ) 2 (H 2 O) 4 ]. The differences are noted between the crystal structures and coordination modes of these two MOFs, which are responsible for their semiconductor properties, where structural control over the bandgap is desirable. Hydrogen bonding is present in only one of the compounds, suggesting it has a slightly higher structural stability. 
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  5. Floorplans often require considering numerous factors, from the layout size to cost, numeric attributes such as room sizes, and other intrinsic properties such as connectivity between visible regions. Representing these complex factors is challenging, but doing so in a representative and efficient way can enable new modes of design exploration. Existing image and graph-based approaches of floorplans’ representation often failed to consider low-level space semantics, structural features, and space utilization with respect to its future inhabitants, which are all the critical elements to analyze design layouts. We present a latent-space representation of floorplans using gated recurrent unit variational autoencoder (GRU-VAE), where floorplans are represented as attributed graphs (encoded with the abovementioned features). Two local search approaches are presented to efficiently explore the latent space for optimizing and generating new floorplans for the given environment. Semantic, structural, and visibility metrics are evaluated individually and as a combined objective for optimizations.

     
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